Jim
Checking water pump rotation, ignition timing and actual temp with heat gun as suggested above should be checked.
Other possibility’s and thoughts.
Thermostat installed upside down.
Lower radiator hose collapsing. Does the lower hose a wire spring installed?
Running the engine without a pressure cap,
Leaking head gasket, cracked head or block. These will allow combustion gasses into the coolant.
A fresh rebuild that has tight pistons will heat up quickly.
Good luck hope you find the problem quickly.
Steve